Inkjet Printed Silver/Graphene Flexible Composite Electrodes Enable High-performance Supercapacitors

2024-11-07
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Inkjet Printed Silver/Graphene Flexible Composite Electrodes Enable High-performance Supercapacitors

Researchers at the Technical University of Liberec (Czech Republic) and Lodz University of Technology (Poland) have developed a silver/graphene flexible composite electrode using inkjet printing technology for high-performance supercapacitors.

The scientists chose rGO as the primary material for the electrode active layer. The rGO active layer was in-situ printed and reduced on the polypropylene non-woven fabric, and silver nanoparticles were simultaneously inserted and reduced to increase the interlayer spacing of the rGO active layer, which effectively reduced the self-stacking effect of rGO and improved the overall electrochemical performance. 

 
The successful in-situ reduction of GO and silver nitrate to rGO and silver nanoparticles was confirmed through morphological, structural, and surface chemical characterization. 

The 4Ag/rGO composite exhibits superior electrical conductivity, with a sheet resistance of 57.39 kΩ/sq., making it suitable for direct use as an electrode. 

In a three-electrode setup, these flexible composite electrodes demonstrated outstanding super capacitive performance, achieving a maximum specific capacitance of 800.30 F/g, excellent bendability, and remarkable cycle stability, with a capacitance retention of 104.9 % after over 2000 charge/discharge cycles at a current density of 0.25 mA/cm2.

Furthermore, the composite electrodes exhibited a high energy density of up to 70.9 Wh/kg at a current density of 0.25 mA/cm2. 

 
The promising capacitive behavior and straightforward manufacturing process position the Ag/rGO hybrid electrodes as a potential material for future applications in next-generation flexible and wearable electronics.

Read the original article on Graphene-Info.

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