From household lighting to mobile phone displays, from pinpoint lighting needed for endoscopy procedures to light source to grow vegetables in Space, LEDs are everywhere. Yet current high-quality LEDs still need to be processed at high temperatures and using elaborated deposition technologies — which make their production cost expensive.
Scientists have recently realised that metal halide perovskites – semiconductor materials with the same structure as calcium titanate mineral, but with another elemental composition – are extremely promising candidates for next-generation LEDs. These perovskites can be processed into LEDs from solution at room temperature, thus largely reducing their production cost. Yet, the electro-luminescence performance of perovskites in LEDs still has room for improvements.
Led by Professor Andrey Rogach, Chair Professor at the Department of Materials Science and Engineering at CityU, and his collaborator Professor Yang Xuyong from Shanghai University, the team has found a kind of dimmer switch: they could turn one light emission from perovskites to a brighter level!
They worked with two-dimensional (2D) perovskites (also known as Ruddlesden Popper perovskites) and succeeded to realize very efficient and bright LEDs, with best-reported performance on both current efficiency and external quantum efficiency for devices based on this kind of perovskites. This work has now put the perovskite LEDs close on the heels of current commercial display technologies, such as organic LEDs.
Their findings were published in the scientific journal Nature Communications, titled “Smoothing the energy transfer pathway in quasi-2D perovskite films using methanesulfonate leads to highly efficient light-emitting devices”.
The key to the powerful change lies in the addition of around 10% of a simple organic molecule called methanesulfonate (MeS).
In this study, the 2D perovskites used by the team have a nanometre level thickness. The MeS reconstructs the structure of the 2D perovskite nanosheets, while at the same time enhancing exciton energy transfer between sheets of different thicknesses. Both of these changes have greatly enhanced the electro-luminescence of the thicker, green-emitting perovskite sheets within the 2D structure.
The MeS is also useful in reducing the number of defects in the 2D perovskite structure. During the process of light production, where radiative recombination took place, part of the excitons required for the process will be “wasted” in the non-radiative recombination which produces no light. MeS reduces the number of uncoordinated Pb2+ cations, the cause for excitons to undergo the non-radiative recombination, making sure more excitons participating in light production.
The results of the research for producing better LEDs has been encouraging. The brightness of 13,400 candela/m2 at a low applied voltage of 5.5 V, and external quantum efficiency of 20.5% were recorded. This is close to the maximum that many existing LED technologies can achieve, and has almost doubled the external quantum efficiency level of 10.5% reported in their previous study two years ago.
“My CityU team has built-up its expertise on perovskite materials to a very high level in a relatively short period of time, thanks to funding support from Senior Research Fellowship by the Croucher Foundation. And already we see the benefit, especially in the outcomes detailed in this latest publication,” said Professor Rogach.
“The achieved high brightness, excellent colour purity, and commercial-grade operating efficiency mark 2D perovskites as extremely attractive materials for future commercial LEDs, and potentially also display technology. It’s a tangible outcome from both fundamental and applied research into novel nano-scale materials,” he adds.
The co-first authors of the paper in Nature Communications are Kong Lingmei from Shanghai University; Dr Zhang Xiaoyu, Associate Professor at Jilin University who previously worked at CityU as research assistant in Professor Rogach’s group back in 2015; and Li Yunguo, Research Professor at University of Science and Technology of China. Other team members include Dr Stephen V. Kershaw, Research Fellow in Professor Rogach group at CityU; and researchers from Shanghai University, Jilin University, University of Science and Technology of China, Nankai University, Wuhan University and Chinese Academy of Sciences.
Effects of MeS on phase distribution of perovskite films. The yellow path indicates the exciton energy transfer between nanosheets of different thicknesses.
The structure and performance of 2D perovskite LEDs.
Read the original article on City University of Hong Kong.