Oct 25, 2022
(Nanowerk News) Miniaturization of infrared spectrometers will lead to their wider use in consumer electronics, such as smartphones enabling food control, the detection of hazardous chemicals, air pollution monitoring and wearable electronics. They can be used for the quick and easy detection of certain chemicals without using laboratory equipment. Moreover, they can be useful for the detection of counterfeit medical drugs as well as of greenhouse gases such as methane and CO2.
A Team of scientists at Empa, ETH Zurich, EPFL, the University of Salamanca, Spain, the European Space Agency (ESA) and the University of Basel now built a proof-of-concept miniaturized Fourier-transform waveguide spectrometer that incorporates a subwavelength photodetector as a light sensor, consisting of colloidal mercury telluride quantum dot (Hg Te) and compatible with complementary metal-oxide-semiconductor (CMOS) technology, as they report in the recent issue of Nature Photonics ("Integrated photodetectors for compact Fourier-transform waveguide spectrometers").
The experimental setup: A red alignment laser was used to visualize the beam path from the fiber into the optical waveguide and its reflection at a gold mirror. Two microprobes were used to contact the photoconductor, the size of which is in the subwavelength range. (Image: Empa)
This is how the IR spectrometer works: The photodetector, fabricated on top of a surface optical waveguide, consists of a bottom gold electrode at the bottom functioning as a scattering center, a photoactive layer (consisting of colloidal mercury telluride – HgTe – quantum dots), and a top gold electrode. By moving the mirror, the measured photocurrent maps the light intensity of the standing wave. i.e. the IR light. A Fourier transformation of the measured signal gives the optical spectra. (Image: Lars Lüder)
"The monolithic integration of subwavelength IR photodetectors has a tremendous effect on the scaling of Fourier-transform waveguide spectrometers", says Empa researcher Ivan Shorubalko. "But this may also be of great interest for miniaturized Raman spectrometers, biosensors and lab-on-a-chip devices as well as the development of high-resolution snapshot hyperspectral cameras."
The experimental setup: A red alignment laser was used to visualize the beam path from the fiber into the optical waveguide and its reflection at a gold mirror. Two microprobes were used to contact the photoconductor, the size of which is in the subwavelength range. (Image: Empa)
Tremendous effects on spectrometers of different kinds – and in various fields
The resulting spectrometer exhibits a large spectral bandwidth and moderate spectral resolution of 50 cm−1 at a total active spectrometer volume below 100 µm × 100 µm × 100 µm. This ultra-compact spectrometer design allows the integration of optical-analytical measurement instruments into consumer electronics and space devices.
This is how the IR spectrometer works: The photodetector, fabricated on top of a surface optical waveguide, consists of a bottom gold electrode at the bottom functioning as a scattering center, a photoactive layer (consisting of colloidal mercury telluride – HgTe – quantum dots), and a top gold electrode. By moving the mirror, the measured photocurrent maps the light intensity of the standing wave. i.e. the IR light. A Fourier transformation of the measured signal gives the optical spectra. (Image: Lars Lüder)
"The monolithic integration of subwavelength IR photodetectors has a tremendous effect on the scaling of Fourier-transform waveguide spectrometers", says Empa researcher Ivan Shorubalko. "But this may also be of great interest for miniaturized Raman spectrometers, biosensors and lab-on-a-chip devices as well as the development of high-resolution snapshot hyperspectral cameras."
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